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Chemical Fact Sheet

Curium

Chemical Abstract Number (CAS #) 7440-51-9
Analytical Methods 200.8 - 6020
Cm

Synopsis from the CRC Handbook of Chemistry and Physics 92nd Edition 2011-2013

Curium — (Pierre and Marie Curie), Cm; at. wt. (247); at. no. 96; m.p. 1345 °C; sp. gr. 13.51 (calc.); valence 3 and 4. Although curium follows americium in the periodic system, it was actually known before americium and was the third transuranium element to be discovered. It was identified by Seaborg, James, 4-10 The Elements and Ghiorso in 1944 at the wartime Metallurgical Laboratory in Chicago as a result of helium-ion bombardment of 239Pu in the Berkeley, California, 60-inch cyclotron. Visible amounts (30 μg) of 242Cm, in the form of the hydroxide, were first isolated by Werner and Perlman of the University of California in 1947. In 1950, Crane, Wallmann, and Cunningham found that the magnetic susceptibility of microgram samples of CmF3 was of the same magnitude as that of GdF3. This provided direct experimental evidence for assigning an electronic configuration to Cm+3. In 1951, the same workers prepared curium in its elemental form for the first time. Sixteen isotopes of curium are now known. The most stable, 247Cm, with a half-life of 16 million years, is so short compared to the Earth’s age that any primordial curium must have disappeared long ago from the natural scene. Minute amounts of curium probably exist in natural deposits of uranium, as a result of a sequence of neutron captures and β decays sustained by the very low flux of neutrons naturally present in uranium ores. The presence of natural curium, however, has never been detected. 242Cm and 244Cm are available in multigram quantities. 248Cm has been produced only in milligram amounts. Curium is similar in some regards to gadolinium, its rare-earth homolog, but it has a more complex crystal structure. Curium is silver in color, is chemically reactive, and is more electropositive than aluminum. CmO2, Cm2O3, CmF3, CmF4, CmCl3, CmBr3, and CmI3 have been prepared. Most compounds of trivalent curium are faintly yellow in color. 242Cm generates about three watts of thermal energy per gram. This compares to one-half watt per gram of 238Pu. This suggests use for curium as a power source. 244Cm is now offered for sale by the O.R.N.L. at $185/mg plus packing charges. 248Cm is available at a cost of $160/μg, plus packing charges, from the O.R.N.L. Curium absorbed into the body accumulates in the bones, and is therefore very toxic as its radiation destroys the red-cell forming mechanism. The maximum permissible total body burden of 244Cm (soluble) in a human being is 0.3 μCi (microcurie).


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