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Chemical Fact Sheet

Krypton

Chemical Abstract Number (CAS #) 7439-90-9
Analytical Methods N/A
Atomic Symbol Kr

Synopsis from the CRC Handbook of Chemistry and Physics 92nd Edition 2011-2013

Krypton (Gr. kryptos, hidden), Kr; at. wt. 83.798(2); at. no. 36; m.p. 157.36 C; b.p. 153.34 0.10 C; tc 63.67 C; density 3.733 g/L (0 C); valence usually 0. Discovered in 1898 by Ramsay and Travers in the residue left after liquid air had nearly boiled away, krypton is present in the air to the extent of about 1 ppm. The atmosphere of Mars has been found to contain 0.3 ppm of krypton. It is one of the noble gases. It is characterized by its brilliant green and orange spectral lines. Naturally occurring krypton contains six stable isotopes. Thirty other unstable isotopes and isomers are now recognized. The spectral lines of krypton are easily produced and some are very sharp. In 1960 it was internationally agreed that the fundamental unit of length, the meter, should be defined in terms of the orange-red spectral line of 86Kr. This replaced the standard meter of Paris, which was defined in terms of a bar made of a platinum-iridium alloy. In October 1983 the meter was again redefined by the International Bureau of Weights and Measures as being the length of path traveled by light in a vacuum during a time interval of 1/299,792,458 of a second. Solid krypton is a white crystalline substance with a face-centered cubic structure that is common to all the rare gases. While krypton is generally thought of as a noble gas that normally does not combine with other elements, the existence of some krypton compounds has been established. Krypton difluoride has been prepared in gram quantities and can be made by several methods. A higher fluoride of krypton and a salt of an oxyacid of krypton also have been prepared. Molecule-ions of ArKr+ and KrH+ have been identified and investigated, and evidence is provided for the formation of KrXe or KrXe+. Krypton clathrates have been prepared with hydroquinone and phenol. 85Kr has found recent application in chemical analysis. By imbedding the isotope in various solids, kryptonates are formed. The activity of these kryptonates is sensitive to chemical reactions at the surface. Estimates of the concentration of reactants are therefore made possible. Krypton is used in certain photographic flash lamps for highspeed photography. Uses thus far have been limited because of its high cost. Krypton gas presently costs about $690/100 L.


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