SPECTRUM

Chemical Fact Sheet

Platinum

Chemical Abstract Number (CAS #) 7440-06-4

Synonyms

C.I.-77795-; Platin- (German); Platinum-black
Analytical Methods 200.8 - 6020
Atomic Symbol Pt

Synopsis from the CRC Handbook of Chemistry and Physics 92nd Edition 2011-2013

Platinum - (Sp. platina, silver), Pt; at. wt. 195.08(3); at. no. 78; m.p. 1768.4 deg C; b.p. 3825 +/- 100 deg C; sp. gr. 21.45 (20 deg C); valence 1?, 2, 3 or 4. Discovered in South America by Ulloa in 1735 and by Wood in 1741. The metal was used by pre-Columbian Indians. Platinum occurs native, accompanied by small quantities of iridium, osmium, palladium, ruthenium, and rhodium, all belonging to the same group of metals. These are found in the alluvial deposits of the Ural mountains, of Columbia, and of certain western American states. Sperrylite (PtAs2), occurring with the nickel-bearing deposits of Sudbury, Ontario, is the source of a considerable amount of metal. The large production of nickel offsets there being only one part of the platinum metals in two million parts of ore. Platinum is a beautiful silvery-white metal, when pure, and is malleable and ductile. It has a coefficient of expansion almost equal to that of soda-lime-silica glass, and is therefore used to make sealed electrodes in glass systems. The metal does not oxidize in air at any temperature, but is corroded by halogens, cyanides, sulfur, and caustic alkalis. It is insoluble in hydrochloric and nitric acid, but dissolves when they are mixed as aqua regia, forming chloroplatinic acid (H2ptCl6), an important compound. Natural platinum contains six isotopes, one of which, 19OPt, is radioactive with a long half-life. Thirty five other radioactive isotopes and isomers are recognized. The metal is extensively used in jewelry, wire, and vessels for laboratory use, and in many valuable instruments including thermocouple elements. It is also used for electrical contacts, corrosion-resistant apparatus, and in dentistry. Platinum-cobalt alloys have magnetic properties. One such alloy made of 76.7% Pt and 23.3% Co, by weight, is an extremely powerful magnet that offers a B-H (max) almost twice that of Alnico V. Platinum resistance wires are used for constructing high-temperature electric furnaces. The metal is used for coating missile nose cones, jet engine fuel nozzles, etc., which must perform reliably for long periods of time at high temperatures. The metal, like palladium, absorbs large volumes, of hydrogen, retaining it at ordinary temperatures but giving it up at red heat. In the finely divided state platinum is an excellent catalyst, having long been used in the contact process for producing sulfuric acid. It is also used as a catalyst in cracking petroleum products. There is also much current interest in the use of platinum as a catalyst in fuel cells and in its use as antipollution devices for automobiles. Platinum anodes are extensively used in cathodic protection systems for large ships and ocean-going vessels, pipelines, steel piers, etc. Pure platinum wire will glow red hot when placed in the vapor of methyl alcohol. It acts here as a catalyst, converting the alcohol to formaldehyde. This phenomenon has been used commercially to produce cigarette lighters and hand warmers. Hydrogen and oxygen explode in the presence of platinum, The price of platinum has varied widely; more than a century ago it was used to adulterate gold. It was nearly eight times as valuable as gold in 1920. The price in January 1996 was about $400/troy oz. ($13/g), about the same price as gold.
Use Manufacturing apparatus for laboratory and industrial use, thermocouples, platinum resistance thermometers, acidproof containers, electrodes, etc. In dentistry; jewelry; electroplating. As oxidation catalyst in manuf acetic acid, nitric acid from ammonia, manuf sulfuric acid; control of automotive emmissions. Spinnarets for rayon and glass fiber manufacture, permanent magnets. Medication: Platinum metal is used as support for fractured bones.
Apparent Color Silver-gray, lustrous, malleable and ductile metal; face-centered cubic structure. Also prepd in the form of a black powder (platinum black) and as spongy masses (platinum sponge).
Boiling Point 3827 + or - 100 deg C
Melting Point 3827 + or - 100 deg C
Molecular Weight 195.08
Density 21.447 (calc)

Chemical and

Physical Properties

Sp heat 0.0314 cal/g at 0 deg C. Electrical resistivity (20 deg) 10.6 uohm-cm. Platinum occurs naturally mainly as the isotopes (194)Pt, (195)Pt, and (196)Pt.

Environmental

Impact

Through escape of auto emission control catalysts or through use of antitumor chemotherapy agents containing platinum. 0.8 ppb near freeway (Lancaster CA and Los Angeles, CA).

Environmental Fate

Six naturally occurring isotopes: 190 (0.01%); 192 (0.8%); 194 (32.9%) 195 (33.8%); 196 (25.2%); 198 (7.2%); 190 is radioactive: half-life 6.9X10+11 years. Abundance in earth's crust about 0.01 ppm. [R4, 1196] Platinum occurs in native form and in a number of mineral forms, including sperrylite, cooperite, and braggite. Platinum is sometimes found with palladium as the arsenide and selenide. Emissions from catalytic mufflers containing platinum. In New Zealand white rabbits spleen, liver and lung all contained platinum at 100 ug/g (dry wt) and kidney at 120 ug/g (dry/wt). Baseline concentration of platinum in tissues of unexposed people are less than 3 ppb (0.003 ug/g of wet tissue).

Drinking Water

Impact

0.08 ppb near freeway (Lancaster, CA and Los Angeles, CA); < 0.05 ppb mining (Sudbury, Ont)


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